Description
Additional Properties
Hydrolytic Sensitivity 1: no significant reaction with aqueous systems Application Reagent for vinylations via cross-coupling protocols.1,2 Reference 1. Denmark, S. E.; Wang, Z. J. Organomet. Chem. 2001, 624, 372. 2. Denmark, S. E.; Butler, C. R. J. Am. Chem. Soc. 2008, 130, 3690. Safety
Packaging Under Nitrogen Alkenylsilane Cross-Coupling Agent The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile. 1,3,5-Trivinyl-1,3,5
-trimethylcyclotrisi
loxane; D’3; Trimethyltrivinylcyc
lotrisiloxane; Trivinyltrimethylcyc
lotrisiloxane; 2,4,6-Trimethyl-2,4,
6-trivinylcyclotrisi
loxane
Reagent formation of styrenes and dienes.
Undergoes “living” anion ring-opening polymerization
Reagent for vinylations via cross-coupling protocols
Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
