Description
Additional Properties
Hydrolytic Sensitivity 1: no significant reaction with aqueous systems Application Reviewed.1 Asymmetrically allylates prochiral ketones with high ee's.2 Allylates ?-keto esters with high enantioselectivty.3 Reference 1. Scott, W. J.; Moretto, A. F. in Encyclopedia of Reagents for Organic Synthesis 1995, Volume 7, 4830-4831. 2. Wooten, A. J. et al. Org. Lett. 2007, 9, 381. 3. Zheng, K. et al. J. Org. Chem. 2007, 72, 8478. Safety
Packaging Under Nitrogen Organotin Cross-Coupling Agent The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile. Tetravinyltin; Tetraethenylstannane
Stille Coupling vinylation reagent
Source for vinyl lithium
Polymerization catalyst
Asymmetrically allylates prochiral ketones with high ee’s
Allylates α-keto esters with high enantioselectivty
Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
