Description
Additional Properties
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents Application Treated onto silica to prepare a fluorinated surface for the embedding of a catalyst for Bonded Fluorous Phase Catalysis (BFPC) used in dehydrogenative silylation of alcohols.1 Forms self-assembled monolayer resists that align nanowire arrays.2 Reference 1. Biffis, A.; Zecca, M.; Basato, M. Green Chemistry, 2003, 5, 170 and Biffis, A.; Braga, M.; Basato, M. Adv. Synth. Catal. 2004, 346, 451. 2. Takahashi, T. et al. J. Am. Chem. Soc. 2009, 131, 2102. Safety
Packaged Over Copper
Packaging Under Nitrogen Specialty Silicon-Based Blocking Agent Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure. (Heptadecafluoro-1,1
,2-2-tetrahydradecyl
)dimethylchlorosilan
e; Perfluorodecyl-1H,1H
,2H,2H-dimethylchlor
osilane; (1H,1H,2H,2H-Perfluo
rodecyl)dimethylchlo
rosilane
Packaged over copper powder
Potential blocking agent for fluorous phase synthesis
Summary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochure
Treated onto silica to prepare a fluorinated surface for the embedding of a catalyst for Bonded Fluorous Phase Catalysis (BFPC) used in dehydrogenative silylation of alcohols
Forms self-assembled monolayer resists that align nanowire arrays
