Additional Properties
Hydrolytic Sensitivity 7: reacts slowly with moisture/water Application Reacts with ethylene oxide to give ?-hydroxy ketones.1 Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propano
l.2 Hydroboration/oxidat
ion leads to trans-1,2-diols.3 Hydroboration/elimin
ation converts silyl enol ethers to olefins.4 Reference 1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763. 2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739. 3. Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9. 4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005. Safety
Packaging Under Nitrogen
Gelest, Inc.
Done
Datasheet
Description
Additional Properties
Hydrolytic Sensitivity 7: reacts slowly with moisture/water Application Reacts with ethylene oxide to give ?-hydroxy ketones.1 Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propano
l.2 Hydroboration/oxidat
ion leads to trans-1,2-diols.3 Hydroboration/elimin
ation converts silyl enol ethers to olefins.4 Reference 1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763. 2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739. 3. Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9. 4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005. Safety
Packaging Under Nitrogen
Additional Properties
Hydrolytic Sensitivity 7: reacts slowly with moisture/water Application Reacts with ethylene oxide to give ?-hydroxy ketones.1 Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propano
l.2 Hydroboration/oxidat
ion leads to trans-1,2-diols.3 Hydroboration/elimin
ation converts silyl enol ethers to olefins.4 Reference 1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763. 2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739. 3. Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9. 4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005. Safety
Packaging Under Nitrogen
Additional Properties
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Application
Reacts with ethylene oxide to give ?-hydroxy ketones.1 Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propanol.2 Hydroboration/oxidation leads to trans-1,2-diols.3 Hydroboration/elimination converts silyl enol ethers to olefins.4
Reference
1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763. 2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739. 3. Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9. 4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005.
Safety
