Gelest, Inc. DIPHENYLPHOSPHORYL AZIDE OMPH056

Additional Properties Hydrolytic Sensitivity 7: reacts slowly with moisture/water Application Reviewed along with other azides.1 Employed in preparation of macrocyclic lactams.2 Reagent for aziridation of olefins in presence of catalysts.3 Used as a reagent for a modified Curtius reaction.4 Fieser F&F: Vol. 4, p 210; Vol. 5, p 280; Vol. 7, p 138; Vol. 8, p 211; Vol. 10, p 173, Vol. 16, p 160. Reference 1. Swamy, K. C. K. et al. Chem. Rev. 2009, 109, 2551. 2. Qian, L. et al. Tetrahedron Lett. 1990, 31, 6469. 3. Ikeda, L. I. et al. Synthesis 1980, 650. 4. Shiiori, T.; Ninomiya, K.; Yamada, S. J. Am. Chem. Soc. 1972, 94, 6203. Safety Packaging Under Nitrogen