Application
Reagent for conversion of carbanions and enolates to titanates with stereoselectivity.1,2 Provides benzyltriisopropoxyt
itanium compounds suitable for cross-linking to form diarylmethanes or aryl-heteroarylmetha
nes.3 Employed in the enantioselective arylation of aldehydes.4
Fieser
F&F: Vol. 11, p 375; Vol. 14, p 87.
Reference
1. Seigel, C.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 457. 2. Nerz-Stonies, M.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 897. 3. Chang, S-T. et al. Tetrahedron, 2012, 68, 3956. 4. Uenishi, A. et al. Chem. Eur. J. 2013, 19, 4896.
Safety
Packaging Under Nitrogen
Application
Reagent for conversion of carbanions and enolates to titanates with stereoselectivity.1,2 Provides benzyltriisopropoxytitanium compounds suitable for cross-linking to form diarylmethanes or aryl-heteroarylmethanes.3 Employed in the enantioselective arylation of aldehydes.4
Fieser
F&F: Vol. 11, p 375; Vol. 14, p 87.
Reference
1. Seigel, C.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 457. 2. Nerz-Stonies, M.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 897. 3. Chang, S-T. et al. Tetrahedron, 2012, 68, 3956. 4. Uenishi, A. et al. Chem. Eur. J. 2013, 19, 4896.
Safety
