Gelest, Inc. CYCLOTRIMETHYLENEDIMETHYLSILANE SIC2570.0

Additional Properties Hydrolytic Sensitivity 4: no reaction with water under neutral conditions Application Review of synthetic utility.1 Undergoes insertion reactions.2 Undergoes polymerization.3 Undergoes reductive silylation of aldehydes.4 Reacts w/ aldehydes to form 3-substituted 1-sila-2-oxacycohexa nes.5 Reference 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 261-262. 2. Matsumoto, K. et al. Tetrahedron Lett. 1990, 31, 6055. 3. Weyenberg, D. et al. J. Org. Chem. 1965, 30, 2618. 4. Hirano, H. et al. Org. Lett. 2006, 8, 483. 5. Takeyama, Y. et al. Tetrahedron Lett. 1990, 31, 6059. Safety Packaging Under Nitrogen